Olaplex has a numbering system that confuses almost everyone at first, so this edit sorts it out. You will find the treatments, oils and creams, the No.4 and No.5 wash-day line including Olaplex shampoo, and a few other bond builders people ask about.
Olaplex, Explained by Someone Who Keeps Losing Track of the Numbers

Olaplex was founded in 2014 by Dean Christal, with chemists Eric Presley and Craig Hawker behind the product. Christal approached the scientist Craig Hawker, who created the patented molecule Bis-Aminopropyl Diglycol Dimaleate. That is a mouthful, so most people just say bond builder. The idea was to work on the bonds inside hair that color and heat can damage, and it began quietly: between 2014 and 2018 the line had two backbar products, No. 1 and No. 2, and one take-home product, No. 3.
That is why the numbers feel strange. They were a salon sequence first, and they grew into a shelf. Olaplex went on to list on Nasdaq on 30 September 2021, but I find the origin more useful than the finance, because it tells you the products were built for professionals who wanted a plan.
Here is the plan for the grid above. No. 0 is the intensive treatment, the one for hair that has had a rough season. N°.0.5 is aimed at the scalp, the odd one out. No. 6 Bond Smoother is a styling cream, No. 7 is a bonding oil and No. 9 is a serum, both with heat protection, and No.10 is a curl-defining gel. I use the oil on damp ends before blow-drying, and the cream on air-dry days.
If you only choose two, take No. 0 and one styler, and learn how they feel before you add anything else. Read the directions on the bottle, because the numbered treatments each have their own timing.

The numbered treatments

No. 7 Bonding Frizz Reduction & Heat Protectant Hair Oil
Olaplex

No. 9 Bond Protector Frizz Reduction & Heat Protectant Hair Serum
Olaplex

No. 6 Bond Smoother Frizz Control Styling Hair Cream
Olaplex

No. 0 Intensive Bond Building Hair Treatment for Deep Repair & Strengthening
Olaplex

N°.0.5 Scalp Longevity Hydrating and Anti-aging Scalp Serum Treatment
Olaplex

No.10 Curl Defining Frizz Reducing Hair Gel
Olaplex

No. 3 Plus Complete Repair Treatment
Olaplex

No. 5 Leave in Moisture & Mend Leave in Conditioner
Olaplex
No.4 shampoos and No.5 conditioners
The No.4 and No.5 pair is the everyday layer: shampoo and conditioner, made for regular washing after the treatments. It is the part of the shelf that actually shows up in your shower three times a week, so it is worth choosing the right version.
No.4 Bond Maintenance Shampoo is for medium hair, and the No.4 Fine version is the volumizing one, which is my answer if hair goes flat the moment it gets wet. The Olaplex shampoo in either version is the everyday wash, made for regular use between treatments. No. 4C is the clarifying one. It removes buildup, so I use it every few weeks, and after a pool day, before I do a deep treatment. It is the reset button when everything starts to feel coated.
No.5 Bond Maintenance Conditioner comes in a medium and a fine version, matching the shampoos. Match them: a fine shampoo with a heavy conditioner will undo the point. I like to use a wide-tooth comb here so the product reaches every strand. Comb conditioner through mid-lengths and ends, leave it for a couple of minutes, then rinse with cooler water for shine.
No.4D Clean Volume Dry Shampoo is the between-washes helper, a weightless detox dry shampoo for roots. It is good on day two, and good when you are traveling and do not want to wash. Just brush it through so it does not sit on the scalp.
No.4 shampoos and No.5 conditioners

No.4 Bond Maintenance Strengthening, Hydrating Hair Repair Shampoo for Medium Hair
Olaplex

No. 4C Bond Maintenance Deep Clean Clarifying Shampoo
Olaplex

No.5 Bond Maintenance Strengthening, Moisturizing Hair Repair Conditioner for Medium Hair
Olaplex

No.4 Fine Bond Maintenance Volumizing and Strengthening Hair Repair Shampoo
Olaplex

No.5 Fine Bond Maintenance Volumizing and Strengthening Hair Repair Conditioner
Olaplex

No.4D Clean Volume Weightless Detox Dry Shampoo
Olaplex

No. 4P Blonde Enhancer Purple Toning Shampoo
Olaplex

No. 5P Blonde Enhancer Purple Toning Conditioner
Olaplex
Other bond builders in the same conversation
Olaplex is far from the only name in the conversation, and it is worth knowing what else people reach for. These are all bond-building or strengthening products, and they behave differently from one another.
K18 Biomimetic Hairscience Leave-In Molecular Repair Hair Mask goes on damp hair and stays in. It is quick, and there is little to rinse, which suits mornings when you have ten minutes. Kérastase Première is a pre-shampoo treatment, so you use it before you wash, and it suits tired lengths. shu uemura Ultimate Reset is a rich mask for very damaged hair, best on a weekend. Oribe Hair Alchemy is a serum that works as a strengthening treatment, and L'Oréal Professionnel's Absolut Repair Molecular mask is another bond-focused option. Bumble and bumble Bond-Building Repair Conditioner is the easiest swap for anyone who wants their normal conditioner to do a little more.
What I would skip: stacking three of these in one wash day. More is not better with bond builders, and too many layers can leave hair heavy, stiff or coated. Pick one treatment per wash, watch how your hair feels for a few weeks, and keep a note of what changed. If breakage is sudden or scalp irritation appears, ask a stylist or a doctor before adding another product.
Other bond builders people ask about

Leave-In Molecular Repair Hair Mask
K18 Biomimetic Hairscience

Première Pre-Shampoo Treatment for Bond Building
Kérastase

Ultimate Reset Strengthening Hair Mask for Very Damaged Hair
shu uemura

Hair Alchemy Strengthening Treatment Serum
Oribe

Bond-Building Repair Conditioner
Bumble and bumble

Absolut Repair Molecular Hair Mask for Bond Building
L'Oréal Professionnel

Rapid Repair Bond Builder+ Leave in Mask
Bondi Boost

Caviar Anti-Aging Restructuring Bond Repair Masque
Alterna
A sensible order of operations
Here is how I would run it. Treatment first if you use one, then your shampoo, then conditioner, then a styler with heat protection, and only on wash day.
Start with a single number and add slowly, so you can tell what is actually making the difference, and resist the urge to buy the whole line in one go. A note on your phone with the date and product is plenty. Use clarifying shampoo sparingly, and keep tools on a moderate heat setting, since no product fully forgives a very hot iron. Trim ends on schedule, because a treatment can improve how hair feels, but it cannot rejoin a split. And if your hair keeps snapping, get a stylist to look at it in person. Sleep on a smooth pillowcase, detangle from the ends up while conditioner is in, and let hair air-dry now and then. Those small habits protect whatever the numbered bottles are trying to do.






