The short answer on London: pick one anchor piece, keep the palette to two colours, and let the shoes decide how formal the whole thing reads. The shoulder seam should sit on the bone, not past it.
What to Wear in London?

Why this comes up
The short answer on London: pick one anchor piece, keep the palette to two colours, and let the shoes decide how formal the whole thing reads. The shoulder seam should sit on the bone, not past it. Hold it up to the light. Opacity is the thing product photography hides best. The groups below run from the decision that matters most to the ones you make afterwards.
The Anchor Pieces

SIAN GOLD SILK ORGANZA TEE
dissh.com.au

Lorden Top
Ronny Kobo

Amanda Marina Cropped Top
Agua by Agua Bendita

Skye Burnout Short Sleeve Tee
splendid.com

GUILDO Boatneck Breton Shirt (ECRU / NAVY)
Saint James

LONG SLEEVE BOW SHIRT in Satin Icevine
7 For All Mankind

Soleil Top - Summer Leaves Blue
Faherty
What actually decides it
What decides this is shoulder seam, sleeve length and opacity. Everything else is preference. Two from the first group show the range: dissh.com.au's SIAN GOLD SILK ORGANZA TEE at $182, and Faherty's Soleil Top - Summer Leaves Blue at $74. The first is the considered buy; the second is the one to start with. Hold it up to the light. Opacity is the thing product photography hides best. The shoulder seam should sit on the bone, not past it. A higher price mostly buys materials and finishing, and occasionally it buys nothing at all.
Layers and Outerwear

MIREYA ELM SAGE TEXTURED KNIT JUMPER
dissh.com.au

Daphne Jacket - Chocolate
Lisa Says Gah

Birch Blazer
Ronny Kobo

The Second Wind Jacket - Break The Ice
Mother Denim

Priya Rib Cardigan: Barley
Carve Designs

Franca Long Sleeve Cardigan
Asta Resort

Splendid x @Cellajaneblog Interlock Cardigan
Splendid

SIAN PEAT PINSTRIPE BOMBER JACKET
Dissh
How to wear it
If the top is the point, keep everything below it plain. From the second group, dissh.com.au's MIREYA ELM SAGE TEXTURED KNIT JUMPER ($182) is the one that earns its place, because it works in more than one context without being restyled. The third group is smaller and deliberately narrower, knits, for the decisions you make after the main one. None of this needs the whole group. One piece from each is usually enough.
Our honest take
There are 20 pieces here from 16 brands, $24 to $630, all in stock when this was written. We would not buy all of them, and neither should you. carvedesigns.com's Denise Turtleneck: Grey Heather - FINAL SALE at $24 is the low-risk way in, and aguabyaguabendita.com's Aguamarina Platero Maxi Dress at $630 only makes sense if this is a category you already use constantly. Read as a set, they get you close to London without any single purchase being compulsory. Nothing here is included because it is famous, and price is not used as a proxy for quality anywhere on this page. If you take one thing away: buy the one you can picture using this week, not the one you are saving for later.
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